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Issue 32, 2013
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Slow magnetic relaxation in tris(diphosphanylamido) and tetra(phosphanoamido) dysprosium complexes

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Abstract

Two homoleptic phosphanylamido dysprosium complexes [Li(THF)4][(Ph2PNPh)4Dy] and [Dy{N(PPh2)2}3] have been synthesized. Both have a highly symmetric arrangement of the ligand which is only slightly broken in the solid state by steric and packing effects as a result of the weak coordination of phosphorus atoms to the metal centre. Magnetic properties of these two compounds are similar with both showing slow magnetic relaxation.

Graphical abstract: Slow magnetic relaxation in tris(diphosphanylamido) and tetra(phosphanoamido) dysprosium complexes

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Publication details

The article was received on 24 Apr 2013, accepted on 15 Jun 2013 and first published on 05 Jul 2013


Article type: Paper
DOI: 10.1039/C3DT51078F
Citation: Dalton Trans., 2013,42, 11471-11475
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    Slow magnetic relaxation in tris(diphosphanylamido) and tetra(phosphanoamido) dysprosium complexes

    F. Völcker, Y. Lan, A. K. Powell and P. W. Roesky, Dalton Trans., 2013, 42, 11471
    DOI: 10.1039/C3DT51078F

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