Issue 21, 2013

Slow magnetic relaxation in a cyano-bridged ferromagnetic {FeIIINiII} alternating chain

Abstract

A cyano-bridged ferromagnetic {FeIIINiII} alternating chain {[Fe(pzTp)(CN)3][Ni(chxn)2]}·ClO4·H2O (1) (pzTp = tetrakis(pyrazolyl)borate, chxn = (1R,2R)-1,2-diaminocyclohexane) was synthesized via rational design. Crystal structure analysis and magnetic studies demonstrated that compound 1 had a one-dimensional zigzagging chain-like structure and slow magnetic relaxation.

Graphical abstract: Slow magnetic relaxation in a cyano-bridged ferromagnetic {FeIIINiII} alternating chain

Supplementary files

Article information

Article type
Paper
Submitted
31 Jan 2013
Accepted
11 Mar 2013
First published
12 Mar 2013

Dalton Trans., 2013,42, 7693-7698

Slow magnetic relaxation in a cyano-bridged ferromagnetic {FeIIINiII} alternating chain

D. Dong, Y. Zhang, H. Zheng, P. Zhuang, L. Zhao, Y. Xu, J. Hu, T. Liu and C. Duan, Dalton Trans., 2013, 42, 7693 DOI: 10.1039/C3DT50273B

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