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Issue 16, 2013
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Stoichiometric C–H arylation of tricarbonyl(arene)chromium complexes bearing pyridine directing groups

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Abstract

Differentially substituted Cr(CO)3-complexed aryl pyridines have been shown to readily undergo stoichiometric palladation and subsequent arylation using boronic acid nucleophiles. The positioning of the aryl substituents has been shown to be key in governing substrate reactivity, whereby sterically congested compounds prevent the geometry required for cyclometallation.

Graphical abstract: Stoichiometric C–H arylation of tricarbonyl(arene)chromium complexes bearing pyridine directing groups

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Publication details

The article was received on 18 Jan 2013, accepted on 06 Mar 2013 and first published on 06 Mar 2013


Article type: Communication
DOI: 10.1039/C3DT50187F
Citation: Dalton Trans., 2013,42, 5615-5618
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    Stoichiometric C–H arylation of tricarbonyl(arene)chromium complexes bearing pyridine directing groups

    M. J. Fuchter, D. K. Judge, M. Weimar and A. J. P. White, Dalton Trans., 2013, 42, 5615
    DOI: 10.1039/C3DT50187F

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