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Issue 25, 2013
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Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts

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Abstract

The synthesis and structural characterisation of the uranium(IV) amido-borohydrides (N′′)2U{κ2-N(SiMe3)SiMe2CH2BBN-H} and U{κ2-N(SiMe3)SiMe2CH2BBN-H}2, and their activity as pre-catalysts for the polymerisation of isoprene are described.

Graphical abstract: Uranium(iv) amido-borohydrides as highly active diene polymerisation catalysts

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Publication details

The article was received on 14 Jan 2013, accepted on 22 Mar 2013 and first published on 10 Apr 2013


Article type: Paper
DOI: 10.1039/C3DT50131K
Citation: Dalton Trans., 2013,42, 9033-9039
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    Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts

    S. M. Mansell, F. Bonnet, M. Visseaux and P. L. Arnold, Dalton Trans., 2013, 42, 9033
    DOI: 10.1039/C3DT50131K

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