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Issue 25, 2013
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Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis

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Abstract

Well defined star copolymers have been prepared by copper-catalyzed atom transfer radical copolymerization of styrene and styryldiphenylphosphine starting from a modified Boltorn™ H30 multifunctional initiator. These polymers and an analogue obtained by debromination of the arm ends with nBu3SnH have been used in combination with [Rh(acac)(CO)2] for the homogeneous phase hydroformylation of 1-octene.

Graphical abstract: Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis

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Publication details

The article was received on 24 Dec 2012, accepted on 20 Feb 2013 and first published on 13 Mar 2013


Article type: Paper
DOI: 10.1039/C3DT33082F
Citation: Dalton Trans., 2013,42, 9148-9156
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    Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis

    A. F. Cardozo, E. Manoury, C. Julcour, J. Blanco, H. Delmas, F. Gayet and R. Poli, Dalton Trans., 2013, 42, 9148
    DOI: 10.1039/C3DT33082F

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