Issue 25, 2013
From the journal:

Dalton Transactions

Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis†

Andrés F. Cardozo,abc   Eric Manoury,ac   Carine Julcour,bc   Jean-François Blanco,bc   Henri Delmas,bc   Florence Gayetac  and  Rinaldo Poli*acd  

* Corresponding authors

a CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France
E-mail: rinaldo.poli@lcc-toulouse.fr
Fax: +33-561553003
Tel: +33-561333173

b CNRS, LGC (Laboratoire de Génie Chimique), 4 Allée Emile Monso, BP 84234, 31030 Toulouse Cedex 4, France

c Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France

d Institut Universitaire de France, 103, bd Saint-Michel, 75005 Paris, France

Abstract

Well defined star copolymers have been prepared by copper-catalyzed atom transfer radical copolymerization of styrene and styryldiphenylphosphine starting from a modified Boltorn™ H30 multifunctional initiator. These polymers and an analogue obtained by debromination of the arm ends with nBu3SnH have been used in combination with [Rh(acac)(CO)2] for the homogeneous phase hydroformylation of 1-octene.

Graphical abstract: Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis

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Article information

DOI
https://doi.org/10.1039/C3DT33082F
Article type
Paper
Submitted
24 Dec 2012
Accepted
20 Feb 2013
First published
13 Mar 2013

Dalton Trans., 2013,42, 9148-9156

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Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis

A. F. Cardozo, E. Manoury, C. Julcour, J. Blanco, H. Delmas, F. Gayet and R. Poli, Dalton Trans., 2013, 42, 9148 DOI: 10.1039/C3DT33082F

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