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Issue 20, 2013
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N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

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Abstract

Investigation of the mechanism of the NHC-initiated hydrosilylation of styryl alcohols in the presence of a dihydrosilane suggests a general base catalysis mechanism and not the activation of the dihydrosilane by the NHC.

Graphical abstract: N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

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Publication details

The article was received on 12 Dec 2012, accepted on 08 Feb 2013 and first published on 08 Feb 2013


Article type: Paper
DOI: 10.1039/C3DT32983F
Citation: Dalton Trans., 2013,42, 7458-7462
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    N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation

    D. Gatineau, Q. Zhao, D. P. Curran, M. Malacria, E. Lacôte, L. Fensterbank and J. Goddard, Dalton Trans., 2013, 42, 7458
    DOI: 10.1039/C3DT32983F

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