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Issue 7, 2014
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N-heterocyclic carbene stabilized phosphaalkenyl(chloro)stannylene

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Abstract

The new phosphaalkenyl(chloro)tin(II) compound NHC–Sn(Cl)[C(SiMe3)[double bond, length as m-dash]PMes*] was isolated and fully characterized including molecular structure determination by a single crystal X-ray diffraction analysis. Its reaction with Me2SAuCl led to the formation of an unprecedented P[double bond, length as m-dash]C-bridged trinuclear gold complex [AuC(SiMe3)[double bond, length as m-dash]PMes*]3 through the transfer of the phosphaalkenyl substituent to the gold atom.

Graphical abstract: N-heterocyclic carbene stabilized phosphaalkenyl(chloro)stannylene

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Publication details

The article was received on 26 Nov 2013, accepted on 12 Dec 2013 and first published on 13 Dec 2013


Article type: Communication
DOI: 10.1039/C3DT53333F
Citation: Dalton Trans., 2014,43, 2718-2721
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    N-heterocyclic carbene stabilized phosphaalkenyl(chloro)stannylene

    T.-G. Kocsor, G. Nemes, N. Saffon, S. Mallet-Ladeira, D. Madec, A. Castel and J. Escudié, Dalton Trans., 2014, 43, 2718
    DOI: 10.1039/C3DT53333F

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