Issue 7, 2014
From the journal:

Dalton Transactions

N-heterocyclic carbene stabilized phosphaalkenyl(chloro)stannylene†

T.-G. Kocsor,ab   G. Nemes,*b   N. Saffon,c   S. Mallet-Ladeira,c   D. Madec,a   A. Castela  and  J. Escudiéa  

* Corresponding authors

a Université de Toulouse, UPS, CNRS, LHFA, UMR 5069, 118 Route de Narbonne, F-31062 Toulouse cedex 09, France

b Facultatea de Chimie şi Inginerie Chimică, Universitatea Babeş-Bolyai, Str. M. Kogălniceanu, Nr: 1, Cluj-Napoca, Romania
E-mail: sgabi@chem.ubbcluj.ro

c Université de Toulouse, UPS, Service Commun Rayons X, ICT-FR2599, 118 Route de Narbonne, F-31062 Toulouse cedex 09, France

Abstract

The new phosphaalkenyl(chloro)tin(II) compound NHC–Sn(Cl)[C(SiMe3)[double bond, length as m-dash]PMes*] was isolated and fully characterized including molecular structure determination by a single crystal X-ray diffraction analysis. Its reaction with Me2SAuCl led to the formation of an unprecedented P[double bond, length as m-dash]C-bridged trinuclear gold complex [AuC(SiMe3)[double bond, length as m-dash]PMes*]3 through the transfer of the phosphaalkenyl substituent to the gold atom.

Graphical abstract: N-heterocyclic carbene stabilized phosphaalkenyl(chloro)stannylene

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Article information

DOI
https://doi.org/10.1039/C3DT53333F
Article type
Communication
Submitted
26 Nov 2013
Accepted
12 Dec 2013
First published
13 Dec 2013

Dalton Trans., 2014,43, 2718-2721

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N-heterocyclic carbene stabilized phosphaalkenyl(chloro)stannylene

T.-G. Kocsor, G. Nemes, N. Saffon, S. Mallet-Ladeira, D. Madec, A. Castel and J. Escudié, Dalton Trans., 2014, 43, 2718 DOI: 10.1039/C3DT53333F

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