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Issue 16, 2014
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White light emission by a lanthanide doped Sm(III) framework constructed from 4-sulfobenzoate and 1H-imidazo[4,5-f][1,10]-phenanthroline

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Abstract

The 2D isostructural lanthanide–organic frameworks [Ln(4-SBA)(IP)OH]·1.5H2O (Ln = Sm 1, Eu 2, Gd 3 and Tb 4; 4-SBA = 4-sulfobenzoate and IP = 1H-imidazo[4,5-f][1,10]-phenanthroline) display different luminescent behavior. White light emission was realized by introducing single dopant Eu(III) and codopants Eu(III)/Gd(III) or Eu(III)/Tb(III) into the Sm(III) framework for the first time.

Graphical abstract: White light emission by a lanthanide doped Sm(iii) framework constructed from 4-sulfobenzoate and 1H-imidazo[4,5-f][1,10]-phenanthroline

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Publication details

The article was received on 06 Nov 2013, accepted on 14 Nov 2013 and first published on 15 Nov 2013


Article type: Communication
DOI: 10.1039/C3DT53139B
Citation: Dalton Trans., 2014,43, 5974-5977
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    White light emission by a lanthanide doped Sm(III) framework constructed from 4-sulfobenzoate and 1H-imidazo[4,5-f][1,10]-phenanthroline

    S. Song, X. Li, Y. Zhang, R. Huo and D. Ma, Dalton Trans., 2014, 43, 5974
    DOI: 10.1039/C3DT53139B

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