Jump to main content
Jump to site search

Issue 7, 2014
Previous Article Next Article

(enH2)4.5[In(AsVS4)3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: two thioarsenates(III, V) with mixed-valent optical properties

Author affiliations

Abstract

Two mixed-valent thioarsenates, namely (enH2)4.5[In(AsVS4)3][As2III(μ-S2)S3]Cl (1) and (enH2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

Graphical abstract: (enH2)4.5[In(AsVS4)3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: two thioarsenates(iii, v) with mixed-valent optical properties

Back to tab navigation

Supplementary files

Publication details

The article was received on 29 Oct 2013, accepted on 01 Dec 2013 and first published on 02 Dec 2013


Article type: Communication
DOI: 10.1039/C3DT53048E
Citation: Dalton Trans., 2014,43, 2733-2736
  •   Request permissions

    (enH2)4.5[In(AsVS4)3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: two thioarsenates(III, V) with mixed-valent optical properties

    K. Du, M. Feng, X. Qi, Z. Ma, L. Li, J. Li, C. Du, G. Zou and X. Huang, Dalton Trans., 2014, 43, 2733
    DOI: 10.1039/C3DT53048E

Search articles by author

Spotlight

Advertisements