Jump to main content
Jump to site search

Issue 3, 2014
Previous Article Next Article

Inclusion chemistry of a thiazyl radical in zeolite-Y

Author affiliations

Abstract

High loading of the radical PhCNSSN˙ (1) into faujasite has been achieved via gas phase diffusion. Whilst the large 12 Å pores can accommodate the enthalpically preferred dimer, the smaller pores dictate inclusion as a paramagnetic monomer. Powder X-ray diffraction studies reveal the host framework is unchanged whilst TGA reveal that the void space has high radical loadings. SQUID magnetometry coupled with EPR spectroscopy indicate that the majority of radicals adopt diamagnetic π*–π* dimers consistent with predominant location of 1 as dimers within the large cavities.

Graphical abstract: Inclusion chemistry of a thiazyl radical in zeolite-Y

Back to tab navigation
Please wait while Download options loads

Publication details

The article was received on 20 Oct 2013, accepted on 30 Oct 2013 and first published on 30 Oct 2013


Article type: Paper
DOI: 10.1039/C3DT52956H
Citation: Dalton Trans., 2014,43, 1332-1337
  •   Request permissions

    Inclusion chemistry of a thiazyl radical in zeolite-Y

    H. J. Cowley, J. J. Hayward, D. R. Pratt and J. M. Rawson, Dalton Trans., 2014, 43, 1332
    DOI: 10.1039/C3DT52956H

Search articles by author