Jump to main content
Jump to site search

Issue 3, 2014
Previous Article Next Article

Rapid synthesis of iron 1,4-naphthalenedicarboxylate by microwave irradiation with enhanced gas sorption

Author affiliations

Abstract

A high quality crystalline porous coordination polymer (PCP), Fe(OH)(1,4-NDC)·2H2O (1,4-NDC = 1,4-naphthalenedicarboxylate), was successfully prepared using a rapid and efficient microwave irradiation method (hereafter termed M-PCP-Fe). It was noteworthy that the microwave irradiation method reduced the reaction time considerably to 1 min, while it took three days for the conventional hydrothermal method to prepare non-uniform crystal morphologies in a one-pot manner (hereafter termed H-PCP-Fe). The effects of microwave irradiation time, temperature and concentration were also investigated. According to the CO2 adsorption isotherms, it was found that M-PCP-Fe had a better performance on CO2 adsorption than H-PCP-Fe under the same conditions. This approach is expected to be widely used in large scale production of PCPs.

Graphical abstract: Rapid synthesis of iron 1,4-naphthalenedicarboxylate by microwave irradiation with enhanced gas sorption

Back to tab navigation
Please wait while Download options loads

Publication details

The article was received on 16 Sep 2013, accepted on 21 Oct 2013 and first published on 22 Oct 2013


Article type: Paper
DOI: 10.1039/C3DT52546E
Citation: Dalton Trans., 2014,43, 1261-1266
  •   Request permissions

    Rapid synthesis of iron 1,4-naphthalenedicarboxylate by microwave irradiation with enhanced gas sorption

    Y. Lou, J. Chen, J. Jiang and Q. Bao, Dalton Trans., 2014, 43, 1261
    DOI: 10.1039/C3DT52546E

Search articles by author