A porous sodalite-type MOF based on tetrazolcarboxylate ligands and [Cu4Cl]7+ squares with open metal sites for gas sorption

Dongmei Wang; Tingting Zhao; Guanghua Li; Qisheng Huo; Yunling Liu

doi:10.1039/C3DT52509K

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A porous sodalite-type MOF based on tetrazolcarboxylate ligands and [Cu₄Cl]⁷⁺ squares with open metal sites for gas sorption†

Dongmei Wang,^a Tingting Zhao,^a Guanghua Li,^a Qisheng Huo^a and Yunling Liu*^a

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* Corresponding authors

^a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
E-mail: yunling@jlu.edu.cn
Fax: +86-431-85168624
Tel: +86-431-85168614

Abstract

A porous sodalite-type metal–organic framework based on tetrazolcarboxylate ligands and [Cu₄Cl]⁷⁺ squares was successfully synthesized, which exhibited permanent porosity and high adsorption abilities of H₂, CO₂ and organic chemical pollutants.

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Article information

DOI: https://doi.org/10.1039/C3DT52509K
Article type: Communication
Submitted: 12 Sep 2013
Accepted: 27 Nov 2013
First published: 03 Dec 2013

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Dalton Trans., 2014,43, 2365-2368

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A porous sodalite-type MOF based on tetrazolcarboxylate ligands and [Cu₄Cl]⁷⁺ squares with open metal sites for gas sorption

D. Wang, T. Zhao, G. Li, Q. Huo and Y. Liu, Dalton Trans., 2014, 43, 2365 DOI: 10.1039/C3DT52509K

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Dalton Transactions