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Issue 43, 2013
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A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap

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Abstract

A three-dimensional coordination polymer based on a manganese-doped polyoxotitanate nanocluster, {Ti13Mn4O16[MeC(CH2O)3]4(OEt)12Br4}∞, has been synthesized under solvothermal conditions. It is the first framework of doped polyoxotitanate nanoclusters reported in the literature. Compared with anatase, its band gap is reduced from 3.19 to 2.57 eV.

Graphical abstract: A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap

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Publication details

The article was received on 13 Aug 2013, accepted on 01 Sep 2013 and first published on 02 Sep 2013


Article type: Communication
DOI: 10.1039/C3DT52218K
Citation: Dalton Trans., 2013,42, 15285-15287
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    A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap

    Y. Chen, J. D. Sokolow, E. Trzop and P. Coppens, Dalton Trans., 2013, 42, 15285
    DOI: 10.1039/C3DT52218K

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