Issue 43, 2013
From the journal:

Dalton Transactions

A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap†

Yang Chen,*a   Jesse D. Sokolow,a   Elzbieta Trzopa  and  Philip Coppens*a  

* Corresponding authors

a Chemistry Department, University at Buffalo, SUNY, Buffalo, New York 14260-3000, USA
E-mail: coppens@buffalo.edu, ychen37@buffalo.edu
Fax: +1-716-645-6948
Tel: +1-716-645-4273

Abstract

A three-dimensional coordination polymer based on a manganese-doped polyoxotitanate nanocluster, {Ti13Mn4O16[MeC(CH2O)3]4(OEt)12Br4}∞, has been synthesized under solvothermal conditions. It is the first framework of doped polyoxotitanate nanoclusters reported in the literature. Compared with anatase, its band gap is reduced from 3.19 to 2.57 eV.

Graphical abstract: A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap

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Article information

DOI
https://doi.org/10.1039/C3DT52218K
Article type
Communication
Submitted
13 Aug 2013
Accepted
01 Sep 2013
First published
02 Sep 2013

Dalton Trans., 2013,42, 15285-15287

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A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap

Y. Chen, J. D. Sokolow, E. Trzop and P. Coppens, Dalton Trans., 2013, 42, 15285 DOI: 10.1039/C3DT52218K

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