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Issue 1, 2014
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Covalent binding of a nickel macrocyclic complex to a silica support: towards an electron exchange column

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Abstract

Ni(II)L2, L2 = 1-propyl-1,3,5,8,12-pentaazacyclotetradecane, was covalently bound to a silica support. This complex can be reversibly oxidized to the corresponding Ni(III) complex. The latter complex is relatively long lived. Therefore electron exchange columns based on this material can be prepared.

Graphical abstract: Covalent binding of a nickel macrocyclic complex to a silica support: towards an electron exchange column

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Publication details

The article was received on 19 Jul 2013, accepted on 13 Sep 2013 and first published on 13 Sep 2013


Article type: Paper
DOI: 10.1039/C3DT51962G
Citation: Dalton Trans., 2014,43, 103-110
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    Covalent binding of a nickel macrocyclic complex to a silica support: towards an electron exchange column

    S. Attia, A. Shames, I. Zilbermann, G. Goobes, E. Maimon and D. Meyerstein, Dalton Trans., 2014, 43, 103
    DOI: 10.1039/C3DT51962G

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