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Issue 38, 2013
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Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand

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Abstract

Formal substitution of the central carbon by silicon within the tetrahedral tetrakis(4-tetrazolylphenyl)methane linker in a copper-based MOF is shown to uniquely influence the structure of the resultant MOF, affecting the orientation of the metal-based nodes and leading to an increase in unit-cell volume and solvent accessible void space.

Graphical abstract: Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand

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Publication details

The article was received on 16 Jul 2013, accepted on 09 Aug 2013 and first published on 20 Aug 2013


Article type: Communication
DOI: 10.1039/C3DT51863A
Citation: Dalton Trans., 2013,42, 13806-13808
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    Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand

    I. Timokhin, J. Baguña Torres, A. J. P. White, P. D. Lickiss, C. Pettinari and R. P. Davies, Dalton Trans., 2013, 42, 13806
    DOI: 10.1039/C3DT51863A

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