A porous Mn(V) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO2 sorption

Michael J. Murphy; Deanna M. D'Alessandro; Cameron J. Kepert

doi:10.1039/C3DT51721G

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A porous Mn(v) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO₂ sorption†

Michael J. Murphy,^a Deanna M. D'Alessandro^a and Cameron J. Kepert*^a

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^a School of Chemistry, The University of Sydney, NSW, Australia
E-mail: cameron.kepert@sydney.edu.au
Fax: +61 (2) 9351-3329
Tel: +61 (0)2 9351-7482

Abstract

A new coordination framework material, [Zn{MnN(CN)₄(H₂O)}]·2H₂O·MeOH, has been characterised crystallographically and the effect of a terminal nitride on the N₂, H₂ and CO₂ sorption capacities of the material assessed through porosimetery measurements and DRIFTS.

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Article information

DOI: https://doi.org/10.1039/C3DT51721G
Article type: Communication
Submitted: 27 Jun 2013
Accepted: 31 Jul 2013
First published: 01 Aug 2013

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Dalton Trans., 2013,42, 13308-13310

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A porous Mn(V) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO₂ sorption

M. J. Murphy, D. M. D'Alessandro and C. J. Kepert, Dalton Trans., 2013, 42, 13308 DOI: 10.1039/C3DT51721G

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Dalton Transactions