Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Tuesday 19th September 2017 from 8.00am to 4.00pm (BST).

During this time our website performance may be temporarily affected. If you have any questions please use the feedback button available under our menu button. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 41, 2013
Previous Article Next Article

Reversible insertion of carbon dioxide into Pt(II)–hydroxo bonds

Author affiliations

Abstract

The reactivity of three monomeric diimine Pt(II) hydroxo complexes, (NN)Pt(OH)R (NN = bulky diimine ligand; R = OH, 1-OH; R = C6H5, 1-Ph; R = CH3, 1-Me) towards carbon dioxide has been investigated. Insertion into the Pt–OH bonds was found to be facile and reversible at low temperature for all compounds; the reaction with bis-hydroxide 1-OH gives an isolable κ2-carbonato compound 2, with elimination of water.

Graphical abstract: Reversible insertion of carbon dioxide into Pt(ii)–hydroxo bonds

Back to tab navigation

Supplementary files

Publication details

The article was received on 25 Jun 2013, accepted on 27 Jul 2013 and first published on 29 Jul 2013


Article type: Paper
DOI: 10.1039/C3DT51701B
Citation: Dalton Trans., 2013,42, 14742-14748
  •   Request permissions

    Reversible insertion of carbon dioxide into Pt(II)–hydroxo bonds

    T. L. Lohr, W. E. Piers and M. Parvez, Dalton Trans., 2013, 42, 14742
    DOI: 10.1039/C3DT51701B

Search articles by author

Spotlight

Advertisements