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Proton-exchange mechanism of specific Cs+ adsorption via lattice defect sites of Prussian blue filled with coordination and crystallization water molecules

M. Ishizaki,a   S. Akiba,a   A. Ohtani,a   Y. Hoshi,a   K. Ono,a   M. Matsuba,a   T. Togashi,a   K. Kananizuka,a   M. Sakamoto,ab   A. Takahashi,b   T. Kawamoto,b   H. Tanaka,b   M. Watanabe,c   M. Arisaka,c   T. Nankawad and   M. Kurihara*ab  
Corresponding authors
Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa-machi, Yamagata 990-8560, Japan
Nanosystem RI, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8565, Japan
Fax: +81-23-628-4606
Tel: +81-23-628-4606
Research Group for Radiochemistry, Nuclear Science and Engineering Directorate, Japan Atomic Energy Agency, 2-4 Shirakata Shirane, Tokai-mura, Naka-gun, Japan
Department of Decommissioning and Waste Management, Japan Atomic Energy Agency, 2-4 Shirakata Shirane, Tokai-mura, Naka-gun, Ibaraki 319-1195, Japan
Dalton Trans., 2013,42, 16049-16055

DOI: 10.1039/C3DT51637G
Received 20 Jun 2013, Accepted 22 Jul 2013
First published online 22 Jul 2013

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