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Proton-exchange mechanism of specific Cs+ adsorption via lattice defect sites of Prussian blue filled with coordination and crystallization water molecules

M. Ishizaki,a   S. Akiba,a   A. Ohtani,a   Y. Hoshi,a   K. Ono,a   M. Matsuba,a   T. Togashi,a   K. Kananizuka,a   M. Sakamoto,ab   A. Takahashi,b   T. Kawamoto,b   H. Tanaka,b   M. Watanabe,c   M. Arisaka,c   T. Nankawad and   M. Kurihara*ab  
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a
Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa-machi, Yamagata 990-8560, Japan
b
Nanosystem RI, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8565, Japan
E-mail: kurihara@sci.kj.yamagata-u.ac.jp;
Fax: +81-23-628-4606 ;
Tel: +81-23-628-4606
c
Research Group for Radiochemistry, Nuclear Science and Engineering Directorate, Japan Atomic Energy Agency, 2-4 Shirakata Shirane, Tokai-mura, Naka-gun, Japan
d
Department of Decommissioning and Waste Management, Japan Atomic Energy Agency, 2-4 Shirakata Shirane, Tokai-mura, Naka-gun, Ibaraki 319-1195, Japan
Dalton Trans., 2013,42, 16049-16055

DOI: 10.1039/C3DT51637G
Received 20 Jun 2013, Accepted 22 Jul 2013
First published online 22 Jul 2013

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