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Issue 31, 2013
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Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

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Abstract

The sequential addition of H+ and H ions to [Mo2Cp2(μ–κ2P,S1P4-SPMes*)(CNtBu)(CO)2] (Mes* = 2,4,6-C6H2tBu3) completes a hydrocarbation or hydronitration of the uncoordinated C[double bond, length as m-dash]C bond of the Mes* ring, yielding new ligands with thiophosphinidene and aldimine or aminocarbene functions tethered to a η4-cyclohexadiene ring. The H ion first attacks a Cp group to give a cyclopentadiene complex which evolves via a hydride intermediate.

Graphical abstract: Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

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Publication details

The article was received on 24 May 2013, accepted on 20 Jun 2013 and first published on 28 Jun 2013


Article type: Communication
DOI: 10.1039/C3DT51562A
Citation: Dalton Trans., 2013,42, 11039-11042
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    Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions

    M. A. Alvarez, B. Alvarez, M. E. García, D. García-Vivó and M. A. Ruiz, Dalton Trans., 2013, 42, 11039
    DOI: 10.1039/C3DT51562A

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