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Issue 45, 2013
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A distorted honeycomb motif in divalent transition metal compounds based on 4-phosphonbenzoic acid and exchange coupled Co(II) and Cu(II): synthesis, structural description and magnetic properties

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Abstract

The first example of a two-dimensional inorganic hybrid material with cobalt as an open-shell transition metal ion and 4-phosphonbenzoic acid as a linker is presented together with its copper analogue. For both metal ions the inorganic part consists of edge-sharing metal–oxygen octahedra leading to a metal honeycomb motif. The magnetic properties of the cobalt compound are reported together with those of the corresponding copper compound based on the remarkably six-coordinated copper(II) ions.

Graphical abstract: A distorted honeycomb motif in divalent transition metal compounds based on 4-phosphonbenzoic acid and exchange coupled Co(ii) and Cu(ii): synthesis, structural description and magnetic properties

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Publication details

The article was received on 03 Jun 2013, accepted on 27 Aug 2013 and first published on 28 Aug 2013


Article type: Paper
DOI: 10.1039/C3DT51437D
Citation: Dalton Trans., 2013,42, 16194-16199
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    A distorted honeycomb motif in divalent transition metal compounds based on 4-phosphonbenzoic acid and exchange coupled Co(II) and Cu(II): synthesis, structural description and magnetic properties

    A. Pütz, L. M. Carrella and E. Rentschler, Dalton Trans., 2013, 42, 16194
    DOI: 10.1039/C3DT51437D

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