Two neutral hexanuclear trigonal prismatic cage molecules have been synthesized by coupling two planar triangular M3pz3-panels, M = Cu(I) and Ag(I), in eclipsed geometry. The 230 Å3 cage volume can be either vacant or occupied by neutral guests. The crystal structures of the M6–cyclohexane and Ag6–S8 host–guest species have been determined.
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