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Issue 30, 2013
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Formation of a 1D-polymeric chain of Hg building blocks through C–C coupling under ambient conditions

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Abstract

A novel C–C coupled 1D-polymeric chain (1) is obtained by reaction of HgCl2 and hmp-H (2-(2-hydroxymethyl pyridine)) (1 : 1) in MeOH at ambient temperature. However, a new class of μ-oxo and μ-chloro bridged polymers (2) has been obtained by altering the metal : ligand ratio to 1 : 2.

Graphical abstract: Formation of a 1D-polymeric chain of Hg building blocks through C–C coupling under ambient conditions

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Publication details

The article was received on 08 May 2013, accepted on 03 Jun 2013 and first published on 05 Jun 2013


Article type: Communication
DOI: 10.1039/C3DT51213D
Citation: Dalton Trans., 2013,42, 10687-10689
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    Formation of a 1D-polymeric chain of Hg building blocks through C–C coupling under ambient conditions

    S. M. Mobin, V. Mishra, P. Ram, A. Birla and P. Mathur, Dalton Trans., 2013, 42, 10687
    DOI: 10.1039/C3DT51213D

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