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Synthesis of iridium and rhodium complexes with new chiral phosphine-NHC ligands based on 1,1′-binaphthyl framework and their application in asymmetric hydrogenation

Peng Gu,a   Jun Zhang,a   Qin Xu*a and   Min Shi*ab  
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a
Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei-Long Road, Shanghai 200237, China
b
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China
E-mail: Mshi@mail.sioc.ac.cn;
Fax: +86-21-64166128 ;
Tel: +86-21-54925137
Dalton Trans., 2013,42, 13599-13606

DOI: 10.1039/C3DT51141C
Received 02 May 2013, Accepted 04 Jul 2013
First published online 05 Jul 2013
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