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Issue 31, 2013
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Direct anion effects on coordination polymerizations: construction and physicochemical properties of 1D, 2D, and 3D copper(II) coordination polymers containing 1,3,5-tris(isonicotinoyloxyethyl)cyanurate

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Abstract

Investigations into the anion effects on the molecular construction of a series of CuX2 (X = BF4, ClO4, and NO3) complexes with 1,3,5-tris(isonicotinoyloxyethyl)cyanurate (L) were carried out. Suitable combinations of tridentate N-donor ligands and a variety of coordination geometries of copper(II) ions produce unique 1D, 2D, and 3D coordination polymers containing open cavities suitable for small chemical species, according to the nature of the polyatomic anions. Indeed, the anion exchangeability and catalytic effects of these polymers are strongly dependent on subtle anion differences, including solubility. Calcination of [Cu(ClO4)(L)(Me2SO)2](ClO4)·2CH2Cl2 crystals preserves its crystallinity at 200 °C, and at 600 °C finally produces stick-shaped microcrystalline copper(II) oxide.

Graphical abstract: Direct anion effects on coordination polymerizations: construction and physicochemical properties of 1D, 2D, and 3D copper(ii) coordination polymers containing 1,3,5-tris(isonicotinoyloxyethyl)cyanurate

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Publication details

The article was received on 30 Apr 2013, accepted on 03 Jun 2013 and first published on 05 Jun 2013


Article type: Paper
DOI: 10.1039/C3DT51124C
Citation: Dalton Trans., 2013,42, 11092-11099
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    Direct anion effects on coordination polymerizations: construction and physicochemical properties of 1D, 2D, and 3D copper(II) coordination polymers containing 1,3,5-tris(isonicotinoyloxyethyl)cyanurate

    W. Hong, H. Lee, T. H. Noh and O. Jung, Dalton Trans., 2013, 42, 11092
    DOI: 10.1039/C3DT51124C

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