Issue 32, 2013
From the journal:

Dalton Transactions

Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: structural characterization of Pd(ii) complexes and their catalytic properties†

Stephan Hohloch,a   Wolfgang Frey,b   Cheng-Yong Suc  and  Biprajit Sarkar*a  

* Corresponding authors

a Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstraße 34-36, Berlin, Germany
E-mail: biprajit.sarkar@fu-berlin.de
Fax: +493083853310
Tel: +493083850919

b Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, Stuttgart, Germany

c Lehn Institute of Functional Materials, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China

Abstract

The exclusive formation of the 1,5-cycloaddition product between azides and alkynes is taken advantage of in generating the first examples of abnormal carbenes from these precursors. This new route provides unprecedented post-functionalization possibilities for such abnormal carbenes.

Graphical abstract: Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: structural characterization of Pd(ii) complexes and their catalytic properties

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Article information

DOI
https://doi.org/10.1039/C3DT51083B
Article type
Communication
Submitted
25 Apr 2013
Accepted
14 May 2013
First published
14 May 2013

Dalton Trans., 2013,42, 11355-11358

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Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: structural characterization of Pd(II) complexes and their catalytic properties

S. Hohloch, W. Frey, C. Su and B. Sarkar, Dalton Trans., 2013, 42, 11355 DOI: 10.1039/C3DT51083B

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