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Issue 23, 2013
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One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation

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Abstract

The reaction of 2-pyridyltetrazolate with [Re(CO)5X] (X = Cl, Br) yielded the formation of an unexpected cyclic metallacalix[3]arene, as revealed by X-ray structural studies, characterised by aqua emission and reversible three-electron oxidation.

Graphical abstract: One-step assembly of Re(i) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation

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Publication details

The article was received on 06 Mar 2013, accepted on 16 Apr 2013 and first published on 17 Apr 2013


Article type: Communication
DOI: 10.1039/C3DT50988E
Citation: Dalton Trans., 2013,42, 8188-8191
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    One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation

    P. J. Wright, S. Muzzioli, B. W. Skelton, P. Raiteri, J. Lee, G. Koutsantonis, D. S. Silvester, S. Stagni and M. Massi, Dalton Trans., 2013, 42, 8188
    DOI: 10.1039/C3DT50988E

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