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Issue 31, 2013
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Facile fabrication and photoluminescence properties of rare-earth-doped Gd2O3 hollow spheres via a sacrificial template method

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Abstract

Rare-earth-doped gadolinium oxide (Gd2O3) hollow spheres were successfully fabricated on a large scale by using PS spheres as sacrificed templates and urea as a precipitating agent, which involved the deposition of an inorganic coating Gd(OH)CO3 on the surface of PS spheres and subsequent calcination in the air. Various approaches including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR), thermogravimetric and differential thermal analysis (TG-DTA), as well as photoluminescence spectroscopies were used to characterize the samples. The results indicate that the sample is composed of uniform hollow Gd2O3 spheres with a mean particle size of about 2.3 μm and these hollow spheres have the mesoporous shell that are composed of a large amount of nanoparticles. The possible mechanism of evolution from PS spheres to the amorphous precursor and to the final hollow Gd2O3 spheres have been proposed. The as-obtained samples show strong light emission with different colors corresponding to different Ln3+ ions under ultraviolet-visible light and electron-beam excitation. Under 980 nm NIR irradiation, Gd2O3:Ln3+ (Ln3+ = Yb3+/Er3+, Yb3+/Tm3+ and Yb3+/Ho3+) exhibit characteristic up-conversion (UC) emissions of red (Er3+, 2H11/2, 4S3/2, 4F9/24I15/2), blue (Tm3+, 1G43H6) and green (Ho3+, 5F4, 5S25I8), respectively. These merits of multicolor emissions in the visible region endow these kinds of materials with potential applications in the field of light display systems, lasers, optoelectronic devices, and MRI contrast agents.

Graphical abstract: Facile fabrication and photoluminescence properties of rare-earth-doped Gd2O3 hollow spheres via a sacrificial template method

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Publication details

The article was received on 06 Apr 2013, accepted on 23 May 2013 and first published on 24 May 2013


Article type: Paper
DOI: 10.1039/C3DT50917F
Citation: Dalton Trans., 2013,42, 11082-11091
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    Facile fabrication and photoluminescence properties of rare-earth-doped Gd2O3 hollow spheres via a sacrificial template method

    Y. Gao, Q. Zhao, Q. Fang and Z. Xu, Dalton Trans., 2013, 42, 11082
    DOI: 10.1039/C3DT50917F

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