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Issue 23, 2013
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Two high-connected metal–organic frameworks based on d10-metal clusters: syntheses, structural topologies and luminescent properties

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Abstract

The d10-metal-oxo clusters connected by the asymmetric tricarboxylate and linear neutral ligands give rise to two novel high-connected MOFs. They feature the highest (3,16)- and (3,8)-connected three-dimensional frameworks based on cube-like octanuclear [Zn82-OH)4(CO2)12] clusters and butterfly-like tetranuclear [Cd43-OH)2(CO2)6] clusters as the secondary building units, respectively.

Graphical abstract: Two high-connected metal–organic frameworks based on d10-metal clusters: syntheses, structural topologies and luminescent properties

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Publication details

The article was received on 12 Mar 2013, accepted on 13 Apr 2013, published on 15 Apr 2013 and first published online on 15 Apr 2013


Article type: Communication
DOI: 10.1039/C3DT50687H
Citation: Dalton Trans., 2013,42, 8183-8187
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    Two high-connected metal–organic frameworks based on d10-metal clusters: syntheses, structural topologies and luminescent properties

    X. Song, S. Song, S. Zhao, Z. Hao, M. Zhu, X. Meng and H. Zhang, Dalton Trans., 2013, 42, 8183
    DOI: 10.1039/C3DT50687H

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