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Issue 26, 2013
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Effect of pore sizes on catalytic activities of arenetricarbonyl metal complexes constructed within Zr-based MOFs

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Abstract

Arenetricarbonyl metal complexes ([–phM(CO)3–] and [–biphM(CO)3–]; ph = phenylene, biph = biphenylene, M = Mo, Cr) constructed within Zr-based MOFs act as highly active and selective catalysts for epoxidation of cyclooctene. Catalytic activities of these complexes are enhanced with increasing the pore sizes of Zr-based MOFs.

Graphical abstract: Effect of pore sizes on catalytic activities of arenetricarbonyl metal complexes constructed within Zr-based MOFs

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Publication details

The article was received on 04 Mar 2013, accepted on 07 May 2013 and first published on 09 May 2013


Article type: Communication
DOI: 10.1039/C3DT50593F
Citation: Dalton Trans., 2013,42, 9444-9447
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    Effect of pore sizes on catalytic activities of arenetricarbonyl metal complexes constructed within Zr-based MOFs

    M. Saito, T. Toyao, K. Ueda, T. Kamegawa, Y. Horiuchi and M. Matsuoka, Dalton Trans., 2013, 42, 9444
    DOI: 10.1039/C3DT50593F

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