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Issue 23, 2013
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Reversible multicomponent self-assembly mediated by bismuth ions

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Abstract

Bi(III) ions are capable of reversible, multicomponent self assembly with suitable tris-coordinate ligands. The nature of the self-assembled structures observed are dependent on the ligand coordination geometry, ligand protonation state and Bi concentration. These assemblies can exploit the maximum number of coordination sites at the Bi vertices (nine), and the self-assembly process has been studied by 1D NMR, Diffusion NMR, ESI-MS and X-ray crystallographic analysis. V-shaped coordinating ligands reversibly form discrete M2L4, M2L3, and M2L2 complexes dependent on ligand/bismuth concentration, whereas a linear coordinating ligand forms a single discrete M3L3 assembly.

Graphical abstract: Reversible multicomponent self-assembly mediated by bismuth ions

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Publication details

The article was received on 01 Mar 2013, accepted on 14 Apr 2013 and first published on 15 Apr 2013


Article type: Paper
DOI: 10.1039/C3DT50578B
Citation: Dalton Trans., 2013,42, 8394-8401
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    Reversible multicomponent self-assembly mediated by bismuth ions

    A. M. Johnson, M. C. Young and R. J. Hooley, Dalton Trans., 2013, 42, 8394
    DOI: 10.1039/C3DT50578B

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