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Issue 27, 2013
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Selective anion encapsulation in solid-state Ln(III)[15-metallacrown-5]3+ compartments through secondary sphere interactions

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Abstract

Secondary sphere interactions from proximal phenyl side chains control the anion selectivity of dimeric Ln(III)[15-MCCu(II),α-aminoHA-5]3+ metallocavitands. CH–O interactions, which are only possible with certain side chains, are sufficient for overcoming an intrinsic energy barrier to binding saturated dicarboxylates in hydrophobic compartments.

Graphical abstract: Selective anion encapsulation in solid-state Ln(iii)[15-metallacrown-5]3+ compartments through secondary sphere interactions

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Publication details

The article was received on 27 Feb 2013, accepted on 04 May 2013 and first published on 22 May 2013


Article type: Communication
DOI: 10.1039/C3DT50535A
Citation: Dalton Trans., 2013,42, 9803-9808
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    Selective anion encapsulation in solid-state Ln(III)[15-metallacrown-5]3+ compartments through secondary sphere interactions

    J. Jankolovits, A. D. Cutland Van-Noord, J. W. Kampf and V. L. Pecoraro, Dalton Trans., 2013, 42, 9803
    DOI: 10.1039/C3DT50535A

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