Modification of Sn/S cages with bis-functionalized ferrocenyl units

Zhiliang You; Dieter Fenske; Stefanie Dehnen

doi:10.1039/C3DT50386K

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Dalton Transactions

Issue 23, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Modification of Sn/S cages with bis-functionalized ferrocenyl units

Zhiliang You,^a Dieter Fenske^b and Stefanie Dehnen*^a

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Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Strasse, D-35043 Marburg, Germany
E-mail: dehnen@chemie.uni-marburg.de ;
Fax: +49 6421 2825653 ;
Tel: +49 6421 2825751

Institut für Anorganische Chemie der Universität Karlsruhe, Engesserstrasse 15, Geb. 30.45, 76131 Karlsruhe, Germany
E-mail: dieter.fenske@aoc1.uni-karlsruhe.de ;
Fax: (+49) 721-608-8440

Dalton Trans., 2013,42, 8179-8182

DOI: 10.1039/C3DT50386K
Received 08 Feb 2013, Accepted 18 Feb 2013
First published online 19 Feb 2013

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Abstract
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Bis-functionalized ferrocenyl units have been attached to organo-functionalized [(R^FSn)₄S₆] double-decker clusters as criss-cross-type intramolecular straps. Two different ways of linking result in different crystal structures and different electrochemical stabilities of the resulting compounds.

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