Slow magnetic relaxation in a cyano-bridged ferromagnetic {FeIIINiII} alternating chain

Da-Peng Dong; Yan-Juan Zhang; Hui Zheng; Peng-Fei Zhuang; Liang Zhao; Yang Xu; Jixiang Hu; Tao Liu; Chun-Ying Duan

doi:10.1039/C3DT50273B

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Dalton Transactions

Issue 21, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Slow magnetic relaxation in a cyano-bridged ferromagnetic {Fe^IIINi^II} alternating chain

Da-Peng Dong,^a^b Yan-Juan Zhang,*^a Hui Zheng,^b Peng-Fei Zhuang,^b Liang Zhao,^b Yang Xu,^b Jixiang Hu,^b Tao Liu*^b and Chun-Ying Duan^b

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Corresponding authors

Chemistry College, Dalian University of Technology, Dalian 116024, China
E-mail: yanjuanzhang@dlut.edu.cn

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China
E-mail: liutao@dlut.edu.cn

Dalton Trans., 2013,42, 7693-7698

DOI: 10.1039/C3DT50273B
Received 31 Jan 2013, Accepted 11 Mar 2013
First published online 12 Mar 2013

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Abstract
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A cyano-bridged ferromagnetic {Fe^IIINi^II} alternating chain {[Fe(pzTp)(CN)₃][Ni(chxn)₂]}·ClO₄·H₂O (1) (pzTp = tetrakis(pyrazolyl)borate, chxn = (1R,2R)-1,2-diaminocyclohexane) was synthesized via rational design. Crystal structure analysis and magnetic studies demonstrated that compound 1 had a one-dimensional zigzagging chain-like structure and slow magnetic relaxation.

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Da-Peng Dong
Yan-Juan Zhang
Hui Zheng
Peng-Fei Zhuang
Liang Zhao
Yang Xu
Jixiang Hu
Tao Liu
Chun-Ying Duan

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Slow magnetic relaxation in a cyano-bridged ferromagnetic {FeIIINiII} alternating chain

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Slow magnetic relaxation in a cyano-bridged ferromagnetic {Fe^IIINi^II} alternating chain