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Issue 21, 2013
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Strong NH⋯S hydrogen bonds in molybdoenzyme models containing anilide moieties

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Abstract

Monooxomolybdenum(IV) and dioxomolybdenum(VI) benzenedithiolate derivatives containing anilide moieties were synthesized and characterized by 1H NMR, UV-visible, IR, and Raman spectroscopies. These complexes exhibit very strong intramolecular NH⋯S hydrogen bonds formed by the acidic anilide NH proton and the desired coplanar structure, resulting in significantly positive redox potential and remarkable acceleration in the reduction of Me3NO in DMF.

Graphical abstract: Strong NH⋯S hydrogen bonds in molybdoenzyme models containing anilide moieties

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Publication details

The article was received on 15 Jan 2013, accepted on 08 Mar 2013 and first published on 08 Mar 2013


Article type: Paper
DOI: 10.1039/C3DT50139F
Citation: Dalton Trans., 2013,42, 7569-7578
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    Strong NH⋯S hydrogen bonds in molybdoenzyme models containing anilide moieties

    T. Okamura, K. Kunisue, Y. Omi and K. Onitsuka, Dalton Trans., 2013, 42, 7569
    DOI: 10.1039/C3DT50139F

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