Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior

Dennis Awasabisah; Nan Xu; Krishna P. Sharmah Gautam; Douglas R. Powell; Michael J. Shaw; George B. Richter-Addo

doi:10.1039/C3DT33109A

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Dalton Transactions

The international journal for inorganic, organometallic and bioinorganic chemistry

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Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; preparation and redox behavior

Dennis Awasabisah,^a Nan Xu,^a Krishna P. Sharmah Gautam,^b Douglas R. Powell,^a Michael J. Shaw^b and George B. Richter-Addo*^a

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Department of Chemistry and Biochemistry, University of Oklahoma, Stephenson Life Sciences Research Center, 101 Stephenson Parkway, Norman, USA
E-mail: grichteraddo@ou.edu ;
Fax: +1 (405) 325-6111 ;
Tel: +1 405 325 4812

Department of Chemistry, Box 1652, Edwardsville, USA

Dalton Trans., 2013, Advance Article

DOI: 10.1039/C3DT33109A
Received 29 Dec 2012, Accepted 17 Feb 2013
First published online 18 Feb 2013

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Abstract
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The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC₆HF₄) and (T(p-OMe)PP)Ru(NO)(OC( [double bond, length as m-dash] O)CF₃) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.