A novel polynuclear Cu(I)–sulfur cluster with 1,2-dithiolate-o-carborane ligands as a potential in vitro antitumour agent and its DNA binding properties

Zhong Han; Jin Jiang; Jing Lu; Dacheng Li; Shuang Cheng; Jianmin Dou

doi:10.1039/C3DT33076A

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Dalton Transactions

Issue 14, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

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A novel polynuclear Cu(I)–sulfur cluster with 1,2-dithiolate-o-carborane ligands as a potential in vitro antitumour agent and its DNA binding properties

Zhong Han,^a Jin Jiang,^a Jing Lu,^a Dacheng Li,^a Shuang Cheng*^b and Jianmin Dou*^a

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Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, P. R. China
E-mail: dougroup@163.com ;
Fax: (+86)635-8239001 ;
Tel: (+86)635-8239298

School of Agriculture, Liaocheng University, Liaocheng, P. R. China
E-mail: chengshuang@lcu.edu.cn

Dalton Trans., 2013,42, 4777-4780

DOI: 10.1039/C3DT33076A
Received 22 Dec 2012, Accepted 06 Feb 2013
First published online 07 Feb 2013

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A novel polynuclear Cu(I)–sulfur cluster, 1 (C₅₄H₆₂B₃₀Cu₆N₈S₆), bearing 1,2-dithiolate-o-carborane and 1,10-phenanthroline ligands was synthesized. The complex displayed rapid, low micromolar in vitro cytotoxicity against a range of epithelial tumour cells and efficient CT-DNA binding.

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Zhong Han
Jin Jiang
Jing Lu
Dacheng Li
Shuang Cheng
Jianmin Dou

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A novel polynuclear Cu(I)–sulfur cluster with 1,2-dithiolate-o-carborane ligands as a potential in vitro antitumour agent and its DNA binding properties

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A novel polynuclear Cu(I)–sulfur cluster with 1,2-dithiolate-o-carborane ligands as a potential in vitro antitumour agent and its DNA binding properties

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