Halide-ion-templated Ag8Cu6 rhombic dodecahedrons: synthesis, structure and reactivity of [Ag8Cu6(CCtBu)12X]BF4 (X = Cl, Br)

Timothy U. Connell; Saman Sandanayake; George N. Khairallah; Jonathan M. White; Richard A. J. O'Hair; Paul S. Donnelly; Spencer J. Williams

doi:10.1039/C3DT33027C

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Dalton Transactions

Issue 14, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Halide-ion-templated Ag₈Cu₆ rhombic dodecahedrons: synthesis, structure and reactivity of [Ag₈Cu₆(CCtBu)₁₂X]BF₄ (X = Cl, Br)

Timothy U. Connell,^a Saman Sandanayake,^a George N. Khairallah,^a Jonathan M. White,^a Richard A. J. O'Hair,*^a Paul S. Donnelly*^a and Spencer J. Williams*^a

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School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, University of Melbourne, Parkville, Australia
E-mail: sjwill@unimelb.edu.au ;
Fax: +61 3 9347 5180 ;
Tel: +61 3 8344 2422

Dalton Trans., 2013,42, 4903-4907

DOI: 10.1039/C3DT33027C
Received 18 Dec 2012, Accepted 16 Jan 2013
First published online 17 Jan 2013

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Halide-templated tert-butylethynide Ag₁₄ complexes undergo reversible exchange with copper(I) to afford a series of mixed Ag_14−nCu_n (n = 1–6) species. Up to six silver atoms in the cluster can be replaced with copper(I) to give a core structure featuring a Ag₈Cu₆ rhombic dodecahedron. These clusters are useful models for investigating the chemical reactivity and photoluminescence of heterometallic d¹⁰–d¹⁰ systems.

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Timothy U. Connell
Saman Sandanayake
George N. Khairallah
Jonathan M. White
Richard A. J. O'Hair
Paul S. Donnelly
Spencer J. Williams

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Dalton Transactions

Halide-ion-templated Ag₈Cu₆ rhombic dodecahedrons: synthesis, structure and reactivity of [Ag₈Cu₆(CCtBu)₁₂X]BF₄ (X = Cl, Br)

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Dalton Transactions

Halide-ion-templated Ag8Cu6 rhombic dodecahedrons: synthesis, structure and reactivity of [Ag8Cu6(CCtBu)12X]BF4 (X = Cl, Br)

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Halide-ion-templated Ag₈Cu₆ rhombic dodecahedrons: synthesis, structure and reactivity of [Ag₈Cu₆(CCtBu)₁₂X]BF₄ (X = Cl, Br)