Jump to main content
Jump to site search

Issue 21, 2013
Previous Article Next Article

Catalytic isomerization of allylic alcohols in water by [RuClCp(PTA)2], [RuClCp(HPTA)2]Cl2·2H2O, [RuCp(DMSO-κS)(PTA)2]Cl, [RuCp(DMSO-κS)(PTA)2](OSO2CF3) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O

Author affiliations

Abstract

The new water soluble complexes [RuClCp(HPTA)2]Cl2·2H2O (2), [RuCp(DMSO-κS)(PTA)2]Cl (3), [RuCp(DMSO-κS)(PTA)2](OSO2CF3) (4) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O (5) have been synthesized and fully characterized by NMR, IR and elemental analysis. The structures of complexes 2·2H22O and 5·2H22O were also characterized by single crystal X-ray determination. The catalytic activity of the complexes and [RuClCp(PTA)2] (1) for the isomerisation in water of 1-octen- to 1-penten-3-ol was assessed and discussed.

Graphical abstract: Catalytic isomerization of allylic alcohols in water by [RuClCp(PTA)2], [RuClCp(HPTA)2]Cl2·2H2O, [RuCp(DMSO-κS)(PTA)2]Cl, [RuCp(DMSO-κS)(PTA)2](OSO2CF3) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 13 Dec 2012, accepted on 23 Feb 2013 and first published on 26 Feb 2013


Article type: Paper
DOI: 10.1039/C3DT32998D
Citation: Dalton Trans., 2013,42, 7622-7630
  •   Request permissions

    Catalytic isomerization of allylic alcohols in water by [RuClCp(PTA)2], [RuClCp(HPTA)2]Cl2·2H2O, [RuCp(DMSO-κS)(PTA)2]Cl, [RuCp(DMSO-κS)(PTA)2](OSO2CF3) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O

    M. Serrano-Ruiz, P. Lorenzo-Luis, A. Romerosa and A. Mena-Cruz, Dalton Trans., 2013, 42, 7622
    DOI: 10.1039/C3DT32998D

Search articles by author