Issue 17, 2013
From the journal:

Dalton Transactions

Assembling novel Cd(ii) complexes with multidentate nitrogen donor ligands obtained in situ from the system: zerovalent copper, cadmium oxide, 1-hydroxymethyl-3,5-dimethylpyrazole and ammonium thiocyanate†

Barbara Barszcz,*a   Joanna Masternaka  and  Wanda Sawka-Dobrowolskab  

* Corresponding authors

a Institute of Chemistry, Jan Kochanowski University, 15G Świętokrzyska Str., 25-406 Kielce, Poland
E-mail: Barbara.Barszcz@ujk.edu.pl

b Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie Str., 50-383 Wrocław, Poland

Abstract

A novel 3D coordination polymer [Cd2(L1)2(SCN)4(MeOH)2]n (1) and monomeric [Cd(NCS)2L2] (2) (L1 = urotropine, L2 = tris(1-(3,5-dimethylpyrazolylmethyl))amine) have been prepared in a one-pot synthesis using 1-hydroxymethyl-3,5-dimethylpyrazole as the starting ligand. The most prominent feature is the formation in situ of the organic compounds: urotropine and scorpionate-tripodal ligands.

Graphical abstract: Assembling novel Cd(ii) complexes with multidentate nitrogen donor ligands obtained in situ from the system: zerovalent copper, cadmium oxide, 1-hydroxymethyl-3,5-dimethylpyrazole and ammonium thiocyanate

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3DT32987A
Article type
Communication
Submitted
12 Dec 2012
Accepted
07 Jan 2013
First published
17 Jan 2013

Dalton Trans., 2013,42, 5960-5963

Permissions

Request permissions

Assembling novel Cd(II) complexes with multidentate nitrogen donor ligands obtained in situ from the system: zerovalent copper, cadmium oxide, 1-hydroxymethyl-3,5-dimethylpyrazole and ammonium thiocyanate

B. Barszcz, J. Masternak and W. Sawka-Dobrowolska, Dalton Trans., 2013, 42, 5960 DOI: 10.1039/C3DT32987A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements