Investigation of the mechanism of the NHC-initiated hydrosilylation of styryl alcohols in the presence of a dihydrosilane suggests a general base catalysis mechanism and not the activation of the dihydrosilane by the NHC.
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Paper
N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation
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a
Institut Parisien de Chimie Moléculaire (UMR CNRS 7201)-FR 2769 UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris, France
E-mail: louis.fensterbank@upmc.fr ;
Fax: (+33) 1-44-27-73-60
E-mail: louis.fensterbank@upmc.fr ;
Fax: (+33) 1-44-27-73-60
b
Department of Chemistry, University of Pittsburgh, 4200 Fifth Avenue, Pittsburgh, USA
c
Université de Lyon, Institut de chimie de Lyon UMR 5265 CNRS-Université Lyon I-ESCPE Lyon, 43 Bd du 11 novembre 1918, 69616 Villeurbanne, France
Dalton Trans., 2013,42, 7458-7462
DOI: 10.1039/C3DT32983F
Received 12 Dec 2012, Accepted 08 Feb 2013
First published online 08 Feb 2013
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