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Issue 22, 2013
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Palladium complexes with stabilized germylene and stannylene ligands

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Abstract

The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylene with (Ph3P)2PdCl2 or Pd(OAc)2. Crystal structures of complexes 2, 8 were determined by single crystal X-ray diffraction analysis. The catalytic activity of complexes 2, 8 was examined in the Suzuki–Miyaura and Heck cross-coupling.

Graphical abstract: Palladium complexes with stabilized germylene and stannylene ligands

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Publication details

The article was received on 29 Nov 2012, accepted on 22 Jan 2013 and first published on 23 Jan 2013


Article type: Paper
DOI: 10.1039/C3DT32867H
Citation: Dalton Trans., 2013,42, 7901-7912
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    Palladium complexes with stabilized germylene and stannylene ligands

    M. M. Kireenko, K. V. Zaitsev, Y. F. Oprunenko, A. V. Churakov, V. A. Tafeenko, S. S. Karlov and G. S. Zaitseva, Dalton Trans., 2013, 42, 7901
    DOI: 10.1039/C3DT32867H

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