Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide

Brian G. Alberding; Samantha E. Brown-Xu; Malcolm H. Chisholm; Arthur J. Epstein; Terry L. Gustafson; Sharlene A. Lewis; Yong Min

doi:10.1039/C3DT32750G

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Dalton Transactions

Issue 15, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Paper

Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide

Brian G. Alberding,^a Samantha E. Brown-Xu,^a Malcolm H. Chisholm,*^a Arthur J. Epstein,^a Terry L. Gustafson,^a Sharlene A. Lewis^a and Yong Min^a

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The Ohio State University, 100 West 18th Avenue, Columbus, USA
E-mail: chisholm@chemistry.ohio-state.edu ;
Fax: +1 614-292-0368 ;
Tel: +1 614-688-3625

Dalton Trans., 2013,42, 5275-5280

DOI: 10.1039/C3DT32750G
Received 18 Nov 2012, Accepted 30 Jan 2013
First published online 04 Feb 2013

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Abstract
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Evidence, based on femtosecond transient absorption and time resolved infrared spectroscopy, is presented for photoinduced charge transfer from the Mo₂δ orbital of the quadruply bonded molecule trans-Mo₂(TⁱPB)₂(BTh)₂, where TⁱPB = 2,4,6-triisopropyl benzoate and BTh = 2,2′-bithienylcarboxylate, to di-n-octyl perylene diimide and di-n-hexylheptyl perylene diimide in thin films and solutions of the mixtures. The films show a long-lived charge separated state while slow back electron transfer, τ_BET [similar] 500 ps, occurs in solution.