A highly selective and sensitive luminescent chemosensor for Zn2+ ions based on cyclometalated platinum(II) complexes

Li-Kun Zhang; Ling-Bao Xing; Bin Chen; Qing-Zheng Yang; Qing-Xiao Tong; Li-Zhu Wu; Chen-Ho Tung

doi:10.1039/C3DT32603A

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Dalton Transactions

Issue 12, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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A highly selective and sensitive luminescent chemosensor for Zn²⁺ ions based on cyclometalated platinum(II) complexes

Li-Kun Zhang,^a Ling-Bao Xing,^b Bin Chen,^b Qing-Zheng Yang,^b Qing-Xiao Tong,*^a Li-Zhu Wu*^b and Chen-Ho Tung^b

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Corresponding authors

Department of Chemistry, Shantou University, Guangdong 515063, P. R. China
E-mail: qxtong@stu.edu.cn ;
Fax: +86 754829 02 508 ;
Tel: +86 754829 02 508

Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: lzwu@mail.ipc.ac.cn ;
Fax: +86 108254 3580 ;
Tel: +86 108254 3580

Dalton Trans., 2013,42, 4244-4247

DOI: 10.1039/C3DT32603A
Received 31 Oct 2012, Accepted 24 Jan 2013
First published online 24 Jan 2013

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A novel luminescent Zn²⁺ ions chemosensor, a cyclometalated platinum(II) bipyridyl acetylide complex, was designed. Of particular significance is that it shows a high sensitivity towards Zn²⁺ ions without interference from other biologically important cations in acetonitrile. The tautomerization of amide favors detecting Zn²⁺ ions among other HTM (heavy and transition metal) ions in aqueous systems.

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Li-Kun Zhang
Ling-Bao Xing
Bin Chen
Qing-Zheng Yang
Qing-Xiao Tong
Li-Zhu Wu
Chen-Ho Tung

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A highly selective and sensitive luminescent chemosensor for Zn²⁺ ions based on cyclometalated platinum(II) complexes