A rare example of a “monomeric” triple transition-metal substituted Keggin anion has been synthesized and characterized by various methods including X-ray crystallography, ESI and MALDI mass spectrometry, electrochemistry, EPR, and SQUID.
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Paper
Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a MnIII-substituted trilacunary Keggin tungstosilicate
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a
Analytical Chemistry, Department of Chemistry – Biomedical Center, Uppsala University, PO Box 599, Uppsala, Sweden
E-mail: denys.shevchenko@kemi.uu.se
E-mail: denys.shevchenko@kemi.uu.se
b
Molecular Biomimetics, Department of Chemistry – Ångström Laboratory, Uppsala University, P.O. Box 523, Uppsala, Sweden
c
V.I. Vernadskii Institute of General and Inorganic Chemistry, NAS, 32-34 Acad. Palladina Ave., Kyiv, Ukraine
d
Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64/13, Kyiv 01601, Ukraine
Dalton Trans., 2013,42, 5130-5139
DOI: 10.1039/C3DT12500A
Received 17 Sep 2012, Accepted 24 Jan 2013
First published online 25 Jan 2013
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Crystal structure data
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