A water soluble Mn(II) polymer with aqua metal bridges

Mònica Fontanet; Montserrat Rodríguez; Isabel Romero; Xavier Fontrodona; Francesc Teixidor; Clara Viñas; Núria Aliaga-Alcalde; Pavel Matějíček

doi:10.1039/C3DT00097D

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Dalton Transactions

Issue 22, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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A water soluble Mn(II) polymer with aqua metal bridges

Mònica Fontanet,^a Montserrat Rodríguez,^a Isabel Romero,*^a Xavier Fontrodona,^a Francesc Teixidor,*^b Clara Viñas,^b Núria Aliaga-Alcalde^c^d and Pavel Matějíček^e

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Departament de Química and Serveis Tècnics de Recerca, Universitat de Girona, Campus de Montilivi, E-17071 Girona, Spain
E-mail: marisa.romero@udg.edu ;
Fax: +34 972 418150 ;
Tel: +34 972 418262

Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus UAB, E-08193 Bellaterra, Spain
E-mail: teixidor@icmab.es

Universitat de Barcelona, Diagonal 645, E-08028 Barcelona, Spain

ICREA-Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, 08193 Bellaterra, Spain

Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030, 128 40 Prague 2, Czech Republic

Dalton Trans., 2013,42, 7838-7841

DOI: 10.1039/C3DT00097D
Received 11 Jan 2013, Accepted 12 Feb 2013
First published online 13 Feb 2013

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The first water soluble and crystallographically determined polynuclear Mn(II) complex, with water molecules bridging every two Mn centers, is reported. This is an unusual feature in 1D oligomer Mn(II) compounds with a nuclearity higher than 2. The polymer structure is largely preserved in water.

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Mònica Fontanet
Montserrat Rodríguez
Isabel Romero
Xavier Fontrodona
Francesc Teixidor
Clara Viñas
Núria Aliaga-Alcalde
Pavel Matějíček

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Dalton Transactions

A water soluble Mn(II) polymer with aqua metal bridges

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