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Issue 21, 2013
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Reduction of carbon monoxide by a tetrakis(aryloxide)diniobium complex having four bridging hydrides

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Abstract

The use of a sterically demanding aryloxide ligand allows us to isolate a tetrakis(aryloxide)diniobium complex bridged by four hydride ligands. This hydride aryloxide undergoes reduction of CO via hydrogenation and deoxygenation, resulting in formation of a methylidene species. Further carbonylation gives a vinylidene complex.

Graphical abstract: Reduction of carbon monoxide by a tetrakis(aryloxide)diniobium complex having four bridging hydrides

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Publication details

The article was received on 27 Sep 2012, accepted on 23 Nov 2012 and first published on 23 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT32798H
Citation: Dalton Trans., 2013,42, 7510-7513
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    Reduction of carbon monoxide by a tetrakis(aryloxide)diniobium complex having four bridging hydrides

    T. Kurogi, Y. Ishida, T. Hatanaka and H. Kawaguchi, Dalton Trans., 2013, 42, 7510
    DOI: 10.1039/C2DT32798H

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