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Issue 6, 2013
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A luminescent single-molecule magnet: observation of magnetic anisotropy using emission as a probe

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Abstract

An assemblage of a Tb(III) ion and two mononuclear [ZnII(L)] complexes as antenna chromophores (H2L: Schiff base ligand) afforded a luminescent single-molecule magnet. The f–f emission spectrum had partially resolved fine structure which provides detailed information on the magnetic anisotropy of the 7F6 ground multiplet of the Tb(III) ion.

Graphical abstract: A luminescent single-molecule magnet: observation of magnetic anisotropy using emission as a probe

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The article was received on 21 Nov 2012, accepted on 12 Dec 2012 and first published on 13 Dec 2012


Article type: Communication
DOI: 10.1039/C2DT32785F
Citation: Dalton Trans., 2013,42, 1987-1990
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    A luminescent single-molecule magnet: observation of magnetic anisotropy using emission as a probe

    K. Yamashita, R. Miyazaki, Y. Kataoka, T. Nakanishi, Y. Hasegawa, M. Nakano, T. Yamamura and T. Kajiwara, Dalton Trans., 2013, 42, 1987
    DOI: 10.1039/C2DT32785F

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