Two novel octamolybdate-based tricarbonyl metal derivatives have been successfully synthesized and characterized, which represent the first two examples of tricarbonyl metal groups attached to a new {Mo8O30} building block.
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Octamolybdate-supported tricarbonyl metal derivatives: [{H2Mo8O30}{M(CO)3}2]8− (M = MnI and ReI)
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a
Polyoxometalates Chemistry Key Laboratory of Henan Province, Henan University, Kaifeng, China
E-mail: jyniu@henu.edu.cn ;
Fax: (+86) 378 3886876 ;
Tel: (+86) 378 3886876
E-mail: jyniu@henu.edu.cn ;
Fax: (+86) 378 3886876 ;
Tel: (+86) 378 3886876
b
Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, China
E-mail: jpwang@henu.edu.cn ;
Fax: (+86) 378 3886876 ;
Tel: (+86) 378 3886876
E-mail: jpwang@henu.edu.cn ;
Fax: (+86) 378 3886876 ;
Tel: (+86) 378 3886876
Dalton Trans., 2013,42, 2696-2699
DOI: 10.1039/C2DT32678G
Received 09 Nov 2012, Accepted 03 Jan 2013
First published online 07 Jan 2013
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